Trifluoromethanesulfonic anhydride CAS#358-23-6

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Chemical Name:Trifluoromethanesulfonic anhydride

CAS No.:358-23-6

Molecular Formula:C2F6O5S2

Molecular weight:282.14

Sample: Available

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Product Details

Products Description of Trifluoromethanesulfonic anhydride CAS#358-23-6

Trifluoromethanesulfonic anhydride is an organic compound with the chemical formula (CF3SO2)2O. It is the anhydride of the strong acid trifluoromethanesulfonic acid and a strong electrophilic reagent that can be used to introduce trifluoromethanesulfonyl groups.



Trifluoromethanesulfonic anhydride Chemical Properties

Melting point 

-80°C

Boiling point 

81-83 °C (lit.)

density 

1.677 g/mL at 25 °C (lit.)

vapor density 

5.2 (vs air)

vapor pressure 

8 mm Hg ( 20 °C)

refractive index 

n20/D 1.321(lit.)

RTECS 

PB2772000

Fp 

81-83°C

storage temp. 

Store below +30°C.

solubility 

Miscible with dichloromethane. Immiscible with hydrocarbons.

form 

Liquid

Specific Gravity

1.677

color 

Clear colorless to light brown

Water Solubility 

reacts violently with water

Sensitive 

Moisture Sensitive

BRN 

1813600

Stability:

Hygroscopic, Moisture Sensitive

InChIKey

WJKHJLXJJJATHN-UHFFFAOYSA-N

LogP

0.3 at 25℃

CAS DataBase Reference

358-23-6(CAS DataBase Reference)

NIST Chemistry Reference

Trifluoromethanesulfonic anhydride(358-23-6)

EPA Substance Registry System

Methanesulfonic acid, trifluoro-, anhydride (358-23-6)

Safety Information

Hazard Codes 

C

Risk Statements 

14-21/22-34-35-22-40

Safety Statements 

26-36/37/39-43-45-8

RIDADR 

UN 3265 8/PG 2

WGK Germany 

3

10-21

Hazard Note 

Corrosive

TSCA 

Yes

HazardClass 

8

PackingGroup 

I

HS Code 

29049020

Toxicity

LD50 orally in Rabbit: 1012 mg/kg


Product Application of Trifluoromethanesulfonic anhydride CAS#358-23-6

As an intermediate, it is widely used in the pharmaceutical industry, proteins, glycosides, vitamins, etc., and Friedel-Crafts benzylation and cyclohexylation catalysts.

2. The plastics industry uses it to catalyze chemical synthesis reactions as a polymerization catalyst and silicone rubber modification.

3. The electronic chemical industry uses it to produce electronically conductive polymers.

4. The fuel industry uses it as a protonation reaction catalyst.

5. The agrochemical industry uses it to synthesize herbicides and growth regulators.

6. Used in the sugar industry.

7. Used in laboratory research for special reactions



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