Phosphoric acidCAS#7664-38-2

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Chemical Name:Phosphoric acid

CAS No7664-38-2

Molecular Formula:H3O4P

Molecular weight:98

Sample: Available

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Product Details

Products Description of Phosphoric acidCAS#7664-38-2

Phosphoric acid is also called orthophosphoric acid (molecular formula H3PO4). The pure product is a colorless, transparent, viscous liquid or orthorhombic crystal, odorless and very sour. 85% phosphoric acid is a colorless, transparent or slightly light-colored, viscous liquid. Melting point 42.35℃, specific gravity 1.70, high boiling point acid, miscible with water in any ratio, boiling point 213℃ (lose 1/2 water), then pyrophosphoric acid is generated. When heated to 300℃, it becomes metaphosphoric acid. Relative density 181.834. It is easily soluble in water and ethanol. Phosphoric acid is a common inorganic acid and a medium-strong acid. Its acidity is weaker than strong acids such as sulfuric acid, hydrochloric acid and nitric acid, but stronger than weak acids such as acetic acid, boric acid and carbonic acid. When phosphoric acid reacts with sodium carbonate at different pH, different acid salts can be generated. It can irritate the skin and cause inflammation, and damage body tissues. Concentrated phosphoric acid has an erosive effect when heated in porcelain. It is hygroscopic and should be stored in a sealed container. Commercially available phosphoric acid is a viscous concentrated solution containing 82% H3PO4. The high viscosity of phosphoric acid solution is due to the presence of hydrogen bonds in the solution.


Phosphoric acid Chemical Properties

Melting point 

~40 °C(lit.)

Boiling point 

158 °C(lit.)

density 

1.685 g/mL at 25 °C(lit.)

vapor density 

3.4 (vs air)

vapor pressure 

2.2 mm Hg ( 20 °C)

refractive index 

n20/D 1.433

FEMA 

2900 | PHOSPHORIC ACID

storage temp. 

no restrictions.

solubility 

H2O: soluble

pka

2.1-7.2-12.3(at 25℃)

form 

Solid or Viscous Liquid

Specific Gravity

1.7

color 

≤10(APHA)

PH

3.06(1 mM solution);2.26(10 mM solution);1.63(100 mM solution);

Odor

Odorless

PH Range

1.5

Water Solubility 

MISCIBLE

λmax

λ: 260 nm Amax: ≤0.05
λ: 280 nm Amax: ≤0.04

Merck 

14,7344

BRN 

1921286

Exposure limits

TLV-TWA 1 mg/m3 (ACGIH, MSHA, and OSHA); TLV-STEL 3 mg/m3 (ACGIH).

Dielectric constant

61.0

InChIKey

NBIIXXVUZAFLBC-UHFFFAOYSA-N

LogP

-2.15

CAS DataBase Reference

7664-38-2(CAS DataBase Reference)

NIST Chemistry Reference

Phosphoric acid(7664-38-2)

EPA Substance Registry System

Phosphoric acid (7664-38-2)

 Safety Information

Hazard Codes 

C,Xn,T,F

Risk Statements 

34-35-22-39/23/24/25-36/38-23/24/25-11

Safety Statements 

7-16-26-36/37-45-36/37/39-1/2-24/25

RIDADR 

UN 3453 8/PG 3

WGK Germany 

3

RTECS 

TB6300000

3-10

TSCA 

Yes

HS Code 

2809 20 00

HazardClass 

8

PackingGroup 

III

Hazardous Substances Data

7664-38-2(Hazardous Substances Data)

Toxicity

ADI 0 to 70 mg / kg (total phosphate content in terms of phosphorus, FAO / WHO, 2001).
GRAS (FDA, § 182.1073, 2000).
LD501530mg / kg (rat, oral).
In case of daily intake of 2 ~ 4 g, it can cause mild diarrhea. The amount of sour agent used as a cola drink is 0.02% to 0.06%.

IDLA

1,000 mg/m3

 

Product Application of Phosphoric acidCAS#7664-38-2

Wet-process phosphoric acid is mainly used to manufacture various phosphates, such as ammonium phosphate, potassium dihydrogen phosphate, disodium hydrogen phosphate, trisodium phosphate, etc. and condensed phosphates. Refined phosphoric acid is used to make calcium hydrogen phosphate for feed. It is used for phosphating of metal surfaces, preparing electrolytic polishing liquid and chemical polishing liquid for polishing of aluminum products. It is used in the pharmaceutical industry to manufacture sodium glycerophosphate, iron phosphate, etc., and is also used to manufacture zinc phosphate as a dental filling adhesive. It is used as a catalyst for the condensation of phenolic resins and a desiccant for the production of dyes and intermediates. It is used in the printing industry to prepare cleaning liquid for wiping off stains on offset color printing plates. It is also used to prepare matchstick impregnation liquid. It is used in the metallurgical industry to produce phosphoric acid refractory mud to increase the life of steelmaking furnaces. It is a coagulant for rubber slurry and a raw material for the production of inorganic adhesives. It is used as metal anti-rust paint in the coating industry.



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